What percent composition means
Formula
% element = (mass of element in one mole ÷ molar mass of compound) × 100
Percent composition answers “how much of this compound's mass comes from each element?” It's how fertiliser bags advertise nitrogen content, how ores are graded, and the standard first step when chemists work backwards from an unknown compound to its empirical formula.
Worked example: water
What percent of water's mass is oxygen?
- Molar mass of H₂O ≈ 18.02 g/mol.
- Oxygen contributes 15.999 g/mol.
- % O = 15.999 ÷ 18.02 × 100
Answer: ≈ 88.8% oxygen (and 11.2% hydrogen) — most of water's mass is oxygen.
Things worth noticing
- Percentages always total 100% (within rounding) — a quick self-check for manual work.
- Atom count ≠ mass percent: water is ⅔ hydrogen atoms but only 11% hydrogen by mass, because oxygen atoms are 16× heavier.
- Hydrates split naturally: in CuSO₄·5H₂O, the water of crystallisation is ~36% of the mass — which is why heating blue copper sulfate loses over a third of its weight.