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32Ge72.631

Germanium (Ge)

Metalloid

Germanium is a brittle grey metalloid that launched the semiconductor era: the first transistors were germanium. Today it serves in fibre optics, infrared lenses and night-vision systems.

Group: 14Period: 4Block: pState at 25 °C: Solid

Position on the periodic table

Fun fact: Before silicon took over, the world's first transistor (1947) was built on germanium.

Atomic properties

Atomic number32
Atomic mass72.6308 amu
Electron configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2
Noble gas shorthand[Ar] 3d10 4s2 4p2
Electrons per shell2, 8, 18, 4
Valence electrons (outer shell)4
Common oxidation states+4, +2
Electronegativity (Pauling)2.01
Covalent radius (approx.)120 pm
First ionization energy762 kJ/mol
Electron affinity118.9 kJ/mol

Physical properties

State at 25 °CSolid
Density5.323 g/cm³
Melting point938.25 °C (1211.4 K)
Boiling point2832.8 °C (3106 K)
Appearancegrayish-white
RadioactiveNo
OriginOccurs naturally

Electron configuration of germanium

Germanium's ground-state electron configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2, usually shortened to [Ar] 3d10 4s2 4p2. Its electrons occupy 4 shells (2, 8, 18, 4), placing it in period 4 of the p-block. The 4 outer-shell electrons drive its bonding behaviour. Explore it interactively in the electron configuration calculator.

Uses of germanium

  • Fibre-optic cores
  • Infrared optics and night-vision lenses
  • Polymerisation catalysts for PET plastic
  • Specialty semiconductors and solar cells

Biological role: None known.

Occurrence: Dispersed in zinc ores and coal; recovered as a refining by-product.

Common compounds of germanium

GeO2

Germanium dioxide

Molar mass →

GeCl4

Germanium tetrachloride

Molar mass →

History and discovery

Discovered: 1886 — Clemens Winkler. Name origin: From Germania, Latin for Germany, homeland of its discoverer.

Clemens Winkler discovered it in 1886, matching Mendeleev's predicted “ekasilicon” almost exactly.

Safety notes

Low toxicity in normal handling; some germanium compounds are harmful if ingested.

Educational context only — always follow your school's laboratory rules and never handle chemicals without proper supervision. See our disclaimer.

Practice questions

Quick practice: Germanium

1. What is the chemical symbol of Germanium?

2. What is the atomic number of Germanium?

3. Which category does Germanium belong to?

4. What is the state of Germanium at room temperature?

5. Which period of the periodic table is Germanium in?

Want more? Try the full quizzes →

Germanium FAQs

What is the atomic number of germanium?

Germanium's atomic number is 32 — every germanium atom has 32 protons in its nucleus.

What is the symbol for germanium?

Ge. From Germania, Latin for Germany, homeland of its discoverer.

Is germanium a metal, nonmetal, or metalloid?

Germanium is classified as a metalloid — an element with properties between metals and nonmetals.

What state is germanium at room temperature?

At about 25 °C, germanium is a solid. It melts at 938.25 °C.

How many valence electrons does germanium have?

Germanium has 4 electrons in its outer shell (shell pattern: 2, 8, 18, 4).

What is germanium used for?

Key uses include: fibre-optic cores; infrared optics and night-vision lenses; polymerisation catalysts for pet plastic.

Related elements

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