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25Mn54.938

Manganese (Mn)

Transition metal

Manganese is an unsung workhorse: nearly all steel contains it, because it removes impurities and adds toughness. Its dioxide has been used as a pigment since cave-painting times.

Group: 7Period: 4Block: dState at 25 °C: Solid

Position on the periodic table

Fun fact: Prehistoric artists used manganese dioxide as a black pigment in cave paintings over 16,000 years ago.

Atomic properties

Atomic number25
Atomic mass54.938 amu
Electron configuration1s2 2s2 2p6 3s2 3p6 4s2 3d5
Noble gas shorthand[Ar] 3d5 4s2
Electrons per shell2, 8, 13, 2
Valence electrons (outer shell)2
Common oxidation states+2, +4, +7
Electronegativity (Pauling)1.55
Covalent radius (approx.)139 pm
First ionization energy717.3 kJ/mol
Electron affinity-50 kJ/mol

Physical properties

State at 25 °CSolid
Density7.21 g/cm³
Melting point1245.8 °C (1519 K)
Boiling point2060.8 °C (2334 K)
Appearancesilvery metallic
RadioactiveNo
OriginOccurs naturally

Electron configuration of manganese

Manganese's ground-state electron configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d5, usually shortened to [Ar] 3d5 4s2. Its electrons occupy 4 shells (2, 8, 13, 2), placing it in period 4 of the d-block. Explore it interactively in the electron configuration calculator.

Uses of manganese

  • Steelmaking (deoxidiser and strengthener)
  • Alkaline and zinc-carbon batteries (MnO₂)
  • Aluminium drink-can alloys
  • Violet glass and ceramic colouring

Biological role: Essential trace element — needed by enzymes for metabolism, bone formation and antioxidant defence.

Occurrence: Twelfth most abundant element in the crust; nodules rich in manganese carpet parts of the deep ocean floor.

Common compounds of manganese

MnO2

Manganese dioxide

Molar mass →

KMnO4

Potassium permanganate

Molar mass →

History and discovery

Discovered: 1774 — Torbern Olof Bergman. Name origin: From Latin magnes via the Magnesia region — historically confused with magnesium and magnetite.

Johan Gottlieb Gahn isolated manganese in 1774 after Scheele recognised it as an element.

Safety notes

Chronic inhalation of manganese dust or fumes harms the nervous system — an occupational hazard for welders.

Educational context only — always follow your school's laboratory rules and never handle chemicals without proper supervision. See our disclaimer.

Practice questions

Quick practice: Manganese

1. What is the chemical symbol of Manganese?

2. What is the atomic number of Manganese?

3. Which category does Manganese belong to?

4. What is the state of Manganese at room temperature?

5. Which period of the periodic table is Manganese in?

Want more? Try the full quizzes →

Manganese FAQs

What is the atomic number of manganese?

Manganese's atomic number is 25 — every manganese atom has 25 protons in its nucleus.

What is the symbol for manganese?

Mn. From Latin magnes via the Magnesia region — historically confused with magnesium and magnetite.

Is manganese a metal, nonmetal, or metalloid?

Manganese is classified as a transition metal.

What state is manganese at room temperature?

At about 25 °C, manganese is a solid. It melts at 1245.8 °C.

What is manganese used for?

Key uses include: steelmaking (deoxidiser and strengthener); alkaline and zinc-carbon batteries (mno₂); aluminium drink-can alloys.

Related elements

Keep working with this element