The weighted average formula
Average atomic mass
average = Σ (isotope mass × fractional abundance)
“Fractional abundance” is the percentage divided by 100. The result is the decimal number printed on the periodic table — an average that usually matches no single real atom.
Worked example: chlorine
Chlorine is 75.76% Cl-35 (34.9689 amu) and 24.24% Cl-37 (36.9659 amu). Find its average atomic mass.
- Cl-35: 34.9689 × 0.7576 = 26.49 amu
- Cl-37: 36.9659 × 0.2424 = 8.96 amu
- Sum: 26.49 + 8.96
Answer: ≈ 35.45 amu — exactly the periodic table value.
Solving backwards for abundances
For a two-isotope element you can reverse the problem: let x be one isotope's fraction, so the other is (1 − x), and solve average = m₁x + m₂(1 − x). Exam favourites include chlorine, boron, copper and silver. The calculator's second mode does this algebra and shows every step.